Polyethylene terephthalate (PET) and its copolymeric variants represent a critical class of thermoplastic polymers widely deployed in packaging, industrial textiles, and consumer products due to their tensile strength, dimensional stability, and chemical resistance. PET materials are broadly categorized into virgin polyester (vPET), derived directly from petrochemical feedstocks, and recycled polyester (rPET), produced via the mechanical or chemical reprocessing of postconsumer polymer waste. While functional performance across both forms remains comparable, structural differences in chain morphology, thermal degradation history, and comonomer distribution persist.